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To study symmetry and its breaking in particle physics, plays very important
role in order to get useful information about the nature. The classification
and arrangements of subatomic particles is also necessary to study particle
physics. Particles which are building blocks of nature are quarks, gluons and
leptons. Baryons and Mesons composed of quarks were arranged by Gell-Mann and
Okubo in their well-known Eight-Fold way up to SU(3) symmetry. Standard model
of particles is composed of these particles. Particles in SU(4) also make some
beautiful patron. These make some multiplets. but all the baryons with spin JP=
3/2+ in these multiplets have not been observed till date. In this paper the
SU(4) multiplets have been organized and studied in an easy and new way. As a
result we obtained some clues about the masses and other characteristics of the
unknown hyperons. These approximations about the characteristics of the
unidentified baryons have been recorded in this article. Mass formula for the
baryon SU(4) multiplets have been obtained.

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